Determination of Enantiomeric Excess in Amine Derivatives with Molecular Self-Assemblies
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چکیده
منابع مشابه
Asymmetric bioreduction of β-ketoesters derivatives by Kluyveromyces marxianus: influence of molecular structure on the conversion and enantiomeric excess.
This study presents the bioreduction of six β-ketoesters by whole cells of Kluyveromyces marxianus and molecular investigation of a series of 13 β-ketoesters by hologram quantitative structure-activity relationship (HQSAR) in order to relate with conversion and enantiomeric excess of β-stereogenic-hydroxyesters obtained by the same methodology. Four of these were obtained as (R)-configuration a...
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15 صفحه اولThe enantiomeric excess determination and dynamic behaviour of cyclic phosphoric acids used for resolution
A method is presented to determine the enantiomeric excess (ee) of phosphoric acids 1, which are extensively used as resolving agents, by means of diastereomeric salt formation with chiral amines. The unexpected dynamic behaviour of these systems leads us to postulate a model, which we refer to as non-reciprocal behaviour.
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2015
ISSN: 1433-7851
DOI: 10.1002/anie.201501736